You mean RIS aka Radeon Image Sharpening, CAS is separate thing implemented by gamedevs, RIS something you can add yourself like NVIDIA Image Sharpening
They're the same thing. Radeon Image Sharpening is implemented at the driver level, so it'll sharpen the entire image. CAS is the same type of sharpening but implemented at the game level, so they can do things like sharpening the image before overlaying the HUD.