I thought that half the others CUs were unavailable because most PS4 games were using the existing shaders is a specific way (because it's more efficient ?). But that the boost mode should theoretically unlock the others CU on games using the CUs in a general 'unified' way.
IRC there are some games that showed impressive framerate improvement in some passages that couldn't be explained by the 31% CPU boost alone, particularly Battlefield 4:
Battlefield 4: >100% framerate improvement in some cases during conquest mode
Project cars: 38% framerate improvement during rain
The talos principle: often 35% framerate improvement