No, the NVIDIA Wayne "Covington" device appears to be running at a much lower GPU clock operating frequency compared to any Tegra 4 production device such as Shield. FYI, there is actually a design verfication engineer at Microsoft by the name of Covington, so this is probably just a test platform for Tegra 4 on Windows. Strangely enough, the OS is being reported in GFXBench as Windows 8 rather than Windows RT, but that could be a simple mistake in the GFXBench database. Assuming that the NVIDIA Wayne Windows test platform is running at half the GPU operating frequency of Tegra 4 production devices, then the GFXB 2.5 performance in Windows should be virtually identical to the GFXB 2.5 performance in Android.
P.S. Even though Shield has a heatsink/fan, the purpose there was not to crank up max operating frequencies to improve benchmark performance vs. thin fanless Tegra 4 tablets/smartphones. The purpose of using a heatsink/fan was to allow gamers to play for hours on end without having to worry about thermal throttling reducing performance over time, and without having to worry about the device becoming warm or hot to the touch over time.