In the short time I was playing around with Starfield on my Steam Deck (only an hour or two), enabling VRS in the starfield menu (not injecting it via the steam deck sidebar) was catastrophic to the visuals and made nearly no difference in performance - I was quite surprised.
I'm sure it was more obvious visually since I was playing at 800p with FSR2 balanced and/or performance, so there weren't very many 'real' pixels to go around, but I was surprised at just how little it did for performance given how much it degraded the image. I've turned it off on my desktop PCs ever since.