As stated above, there are specialized color gamuts for specialized applications, and some of these are larger than the sRGB/Rec.709. Adobe RGB, one of the more common ones, is used by imaging professionals and you'll find it as an option on some digital cameras and scanners. Just be aware that if you use the Adobe gamut, you will also need a display that produces the Adobe gamut, and only a small fraction of consumer displays can do this. If you display an image produced with an Adobe gamut on a monitor with a standard sRGB/Rec.709 gamut, the colors will be incorrect and oversaturated.