Quite the contrary!
See this news from 3DCenter.de:
http://www.3dcenter.org/news/2010-12-02
Scaling of the HD6870: 83%
Scaling of the GTX580: 64%
So a Crossfire System scales up to ~10% better than a SLi System. Yep AMD has improved Crossfire a lot over the years.
Your comparison is a bit flawed as GTX580 is a far more powerful card and thus more prone to system bottlenecks. From the same link:
GeForce GTX 460 1024MB: 79%