OK, I don't know the theory behind this, but I do know that when the VSA-100 did 2x it did not do 45 (or 135) degrees. I assume they had a reason for not doing 45 degrees, since it wasn't any easier to do 25 or whatever it was they ended up doing.
It was my understanding (although I could be mistaken, again) that the 9700 doesn't do 45 degree either, but somewhere around 30.
I think the reason for not doing 45 degrees is so the samples don't line up in neat diagonal stripes, which I believe is more prone to artifacts than the herringbone pattern you get with other sample angles. I think this is supposed to more than make up for favoring the vertical or horizontal component of anti-aliasing.